Llano County was created from Bexar in 1856.
I have taken the Deeds Index from Bexar in the earliest years.
(I can't give a year for any of them. There aren't dates given in the index)

BEXAR COUNTY
DIRECT

GRANTOR GRANTEE PAGE NO.
ARCINIEGA, M. S. A. MAVERICK 1
ARNOLD, F. J. A. NAUENDORF 8
ARNOLD, F. J. A. NAUENDORF 11
ANDRES, JOST- ESTATE M. A. DOOLEY 15
ARNOLD, F. J. G. SCHLEICHER 237
AMEND, FRED G. SCHLEICHER 352
ANDERS, WM. MAX F. BONZANO 247
BEGLEY, JOHN T. T. BAILEY 27
BOWEN, JOHN MARY E. PEACOCK 82
BONZANO, MAX HENRY F. FISHER 249
BELL, E. SELDIN ANSON PORTER 275
BERKEMIER, F. JOHN C. BROWER 335
BONZANO, MAX F. - BY ATTY. B. MILLER 414
CREITZ, CONRAD - ESTATE CARL FLOGE 29
CORRETH, ERNST JOS. H. DEVINE 38
COLLINS, JOHN JOHN D. ANDREWS 40
COLQUHOUN, L.
(This is a variation of Calhoun)
JOHN JAMES 68
COFFEE, WM. B. PETER PAULEY 311
DOOLEY, M. A. WM. FRIEDRICH, ET AL 17
DEAN, WM. B. P. C. JACK 52
DIETRICH, CH. R. - ESTATE F. J. ARNOLD 55
DOOLEY, M. A. WM. FRIEDRICH, ET AL 76
DOOLEY, M. A. G. SCHLEICHER 97
DOOLEY, M. A. WM. FRIEDRICH 121
De CORDOVA, JACOB VICTOR CONSIDERANT 147
De CORDOVA, JACOB JOHN A. SANTERS 151
De CORDOVA, JACOB E. J. HART & CO. 219
DOOLEY, M. A. LUCY P. D. ROBINSON 258
De CORDOVA, JACOB WM. P. GRAVES 260
DOOLEY, M. A. WM. FRIEDRICH, ET AL 271
DOOLEY, M. A. A. NAUENDORF 302
DOOLEY, M. A. LUCY P. C. ROBINSON 371
De CORDOVA, JACOB JOHN D. ANDREWS 432
ESCALERA, MANUEL WM. H. STEELE, ET AL 60
ESCHENBRENNER, W. D. F. J. ARNOLD 73
EGGELING, JULIUS WM. FRIEDRICH 367
FRIEDRICH, WM. H. F. FISHER 19
FLOEGE, CARL ROBERT BECHAM 31
FISHER, HENRY F. G. M. SHERWOOD 42
FLORES, G. S. A. MAVERICK 78
FISHER, HENRY F. B. MILLER 83
FISHER, HENRY F. G. SCHLEICHER 104
FISHER, HENRY F. B. MILLER 106
FISHER, H. F. B. MILLER 115
FEITSAM, GEO. M. A. DOOLEY 119
FEITSAM, GEO. G. SCHLEICHER 240
FRIEDRICH, WM. H. F. FISHER 273
FRIEDRICH, WM. H. F. FISHER 369
FISHER, H. F. GER. EM. CO. 388
FISHER, H. F. THEO. FISHER 394
FISHER, H. F. J. G. GIDDINGS 410
FISHER, H. F. S. W. BAKER 415
GERMAN EM. CO. - BY ATTY. A. NAUENFORD 3
GERMAN EM. CO. " ROBERT BECHEM 33
" " " " G. H. SHERWOOD 42
" " " " A. NAUENDORF 47
" " " " J. EGGLING 58
" " " " J. De CORDOVA 117
GORTARI, ALEJANDRO JAS. H. MORRIS 135
GONZALES, A. JR. ENOCH JONES, ET AL 138
GOODBREAD, PHILLIP THOS. J. DEVINE 140
GEIS, JOHN F. W. GRASSMEYER 142
GERMAN EM. CO. F. W. GRASSMEYER 143
" " " I. A. PASCHAL 158
" " " HENRY RUNGE 162
GEISER, Y. G. JOHN JAMES 171
GARZA, RAFAEL S. A. MAVERICK 193
GERMAN EM. CO. FRANZ MOREAN 205
GROESBECK, JOHN D. JOHN C. FRENCH 256
GERMAN EM. CO. FISHER & MILLER 400
" " " FISHER & MILLER, PLFFS. 417
HENDERSON, J. P. L. COLQUHOUN 67
HELMOUTH, MARTIN Y. G. GEISER 170
HEBERER, GEORGE JOHN H. BROWN 173
HERRERA, TORIVIO E. JONES, ET AL 185
HOUSTON, WM. Y. GEO. S. HOUSTON 234
HARDEMAN, WM. P. & D. PETER PAULEY 311
HARPER, C. A. A. M. DIGNOWITTY 373
HOWARD, R. A. A. A. LOCKWOOD 395
HOHENTHAL, S. L. JOHN NAGLE 424
IMMEL, C. - ESTATE A. NAUENDORF 187
JAIME, PHILIP RAFAEL GARZA 189
JAMES, WILLIAM A. F. BORDEN 196
JAQUES, WM. B. JOHN BOWEN 199
JAEGER, PHIL - ESTATE A. NAUENDORF 200
JUNG, JACOB FRANZ MOREAN 303
JAQUES, WM. B. JOHN BOWEN 263
KRAATZ, LOUIS OLIVIA JOHNSON 208
KARNS, HENRY W. S. & WM. J. BRYAN 209
KARNES, H. W. - ESTATE S. A. MAVERICK 212
KIMPLE, PETER ALEX FERGUSON 216
LEWIS, HENRY M. G.S.WOOD 72
LEWIS, JOHN JOHN W. SMITH 277
LAUDERDALE, J. M. - ESTATE JAS. ROBINSON 281
LUCKIE, S. H. S. A. MAVERICK 293
LEGE, CHAS. L. W. P. HARDEMAN, ET AL 312
MILLER, BURCHARD G. H. SHERWOOD 42
MILLER, BURCHARD HENRY F. FISHER 87
MILLER, BURCHARD WM. ANDERS 89
MILLER, BURCHARD G. SCHLEICHER 92
MILLER, B. M. F. BONZANO 109
MILLER, B. M. F. BONZANO 111
MILLER, B. M. F. BONZANO 113
MORRIS, JAMES H. CHAS. MORGAN 136
MEUSEBACH, JOHN O. F. HERFF 225
MUESEBACH, JOHN O. F. HERFF 227
MILLER, B. - ESTATE JULIUS EHRICSON 244
MILLER, B. - BY ATTY. M. F. BONZANO 251
MILLER, BURCHARD G. SCHLEICHER 255
MARTINEZ A. & WIFE JAS. ROBINSON 289
MONKEN, FRED JAS. FERGUSON 294
MERTZ, C. C. R. HILLEBRAND 295
MEIMAN H. - ESTATE M. A. DOOLEY 299
MILLER, B. GERMAN EM. CO. 388
MILLER, B. THEO FISHER 394
MARTIN, JOHN L. FISHER & MILLER 400
MILLER, B. JOHN G. GIDDINGS 410
MILLER, B. S. W. BAKER 415
To be Continued: